Beschreibung:
A comprehensive and up-to-date overview of alkyne chemistry, taking into account the progress made over the last two decades. The experienced editors are renowned world leaders in the field, while the list of contributors reads like a "e;Who's Who"e; of synthetic organic chemistry. The result is a valuable reference not only for organic chemists at universities and in the chemical industry, but also for biologists and material scientists involved in the modern synthesis of organic compounds and materials.
A comprehensive and up-to-date overview of alkyne chemistry, taking into account the progress made over the last two decades. The experienced editors are renowned world leaders in the field, while the list of contributors reads like a "Who's Who" of synthetic organic chemistry.The result is a valuable reference not only for organic chemists at universities and in the chemical industry, but also for biologists and material scientists involved in the modern synthesis of organic compounds and materials.
IntroductionPART I: CATALYTIC ISOMERIZATION OF ALKYNES1) Redox Isomerization of Propargyl Alcohols to Enones2) Carbophilic Cycloisomerization Reactions of Enynes and Domino Processes3) Alkyne-Alkyne Metathesis ReactionsPART II: CATALYTIC CYCLOADDITION REACTIONS4) Alkyne-Azide Reactions5) Catalytic Cycloaddition ReactionsPART III: CATALYTIC NUCLEOPHILIC ADDITIONS AND SUBSTITUTIONS6) Catalytic Conjugate Additions of Alkynes7) Catalytic Alkyne-Carbonyl Additions8) Catalytic Nucleophilic Addition of Alkynes to Imines: The A3 (Aldehyde-Alkyne-Amine) Coupling9) Sonogashira ReactionsPART IV: OTHER REACTIONS10) Catalytic Dimerization of Alkynes11) The Oxidative Dimerization of Acetylenes and Related Reactions: Synthesis and Applications of Conjugated 1,3-Diynes12) The Alkyne Zipper Reaction in Asymmetric Synthesis